Updated Oct.14/04	

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NUMERICAL ANSWERS TO ASSIGNED TUTORIAL PROBLEM SETS FOR CHEM206
FROM KOTZ & TREICHEL'S CHEMISTRY & CHEMICAL REACTIVITY			
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NOTE:  these answers have NOT been verified.  
NOTE:  "^" means "raised to the power of..." to indicate scientific notation

							
Ch.	Q#	Ans.		Units		SFs	Comments
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13	1						see text
13	17						I2(s): induced dipole - induced dipole
13	17						CH3OH: hydrogen bonding
13	17						I2 & CH3OH:  induced dipole - dipole
13	19a						induced dipole - induced dipole
13	19b						hydrogen bonding
13	19c						dipole - dipole
13	19d						induced dipole - induced dipole
13	21						increasing forces:  He < butane < methanol
13	21						gases at RT/1atm:  He, butane
13	23						HCO2H (formic acid)
13	25	1.99		kJ		3	
13	31						predict bp CH4 < CO < NH3 < SCl2
13	33a						increase
13	33b						increases
13	33c						no change
13	33d						increases
13	51a						induced dipole - induced dipole
13	51b						hydrogen bonding
13	55	6.0x10^1	mol		2	only 17mol is present, so all will evaporate
13	57						ICl (polar molecule)
13	57						krypton (greater molar mass)
13	57						ethanol (hydrogen bonding)
13	59	350		mm Hg		2	
13	59						ethanol
13	59	84		C		2	
13	59						CS2 46C; C2H2OH 78C; C7H16 99C
13	59						CS2 gas; C2H2OHgas; C7H16 liquid
13	61						increasing forces:  CO2 < CH3Cl < HCO2H
13	67						1-propanol (H-bonding) > methyl ethyl ether (dipole-dipole)
13	71						increasing enthalpy of vaporization:  C2H6 < HCl < CH3OH