Updated Mar.02/05 ----------------------------------------------------------------------------------------- NUMERICAL ANSWERS TO ASSIGNED TUTORIAL PROBLEM SETS FOR CHEM206 FROM KOTZ & TREICHEL'S CHEMISTRY & CHEMICAL REACTIVITY ----------------------------------------------------------------------------------------- NOTE: these answers have been verified. #33 is now fixed. NOTE: "^" means "raised to power of..." Ch. Q# Ans. Units SFs Comments ---------------------------------------------------------------- 6 3 text 6 8 text 6 13 399 Cal 3 6 15 136 J/(mol K) 3 6 17 674 J 3 6 21 37.4 C 3 6 25 0.27 J/(g C) 2 6 27 3.30x10^2 kJ 3 6 33 -3.0 kJ 2 6 35 -82.9 kJ 3 6 39 -68 kJ 2 6 43 -96 kJ/mol 2 6 47 -2800 kJ/mol 2 6 51a -43.6 kJ 3 6 51b diagram 6 53 -3.20x10^2 kJ/mol 3 6 59a 5.0x10^-1 kJ 2 6 59b 18 kJ 2 6 59c -6.47 kJ 3 6 59d -4.13 kJ 3 6 65 103.6 kJ 4 6 69 8 kJ 1 water 6 69 10 kJ 1 ethanol 6 73 75.4 g 3 melted 6 79 -27 kJ/mol 2 6 81 -140 kJ/mol 2 6 83a text--Hess's law 6 83b 116.8 kJ 4 6 83c diagram 6 83d Likely reactant-favoured --> delta-H > 0…but entropy? 6 87 Using H2O(l) -- could use H2O(g) data instead --> different answers 6 87 -50.325 kJ/g 5 propane 6 87 -49.482 kJ/g 5 butane 6 87 -47.810 kJ/g 5 gasoline 6 87 -29.684 kJ/g 5 ethanol 6 97a -1.220x10^3 kJ 4 add/sub. only 6 97b diagram 6 101 1.6x10^11 kJ 2 this quantity of E is RELEASED 6 101 38000 tonnes 2 c.f. dynamite